PY3 vs PY12

Comparing monoazo yellow PY3 with diarylide yellow PY12 — chemistry, shade, applications, and selection guide.

PY3 and PY12 are both azo yellows but with distinct chemistry — PY3 is a monoazo (single -N=N- group), PY12 is diarylide (two coupled azo groups). The chemistry difference produces noticeable differences in shade, strength, and price.

Property PY3 PY12
ChemistryMonoazoDisazo (diarylide)
CI CodeCI Pigment Yellow 3CI Pigment Yellow 12
CAS Number6486-23-36358-85-6
ShadeClean greenish yellowReddish yellow / orange-yellow
Tinctorial strengthStandardHigher (diarylide is more concentrated)
Lightfastness5-6 Blue Wool4-5 Blue Wool
Heat stability180-200°C180-200°C
Cost tierStandard (cost-effective)Slightly higher
REACH / banned aminesModern grades certified compliantSome traditional grades fail (benzidine-derived); only certified grades are compliant
Primary useInk, architectural paint, textile printingHigh-strength inks, masterbatch (low-temp polymers)

When to choose PY3

Choose PY3 for cleaner, more greenish shades in inks, architectural paints (interior), textile printing, and rubber compounding where Blue Wool 5-6 lightfastness is sufficient. Cost-effective for high-volume applications.

When to choose PY12

Choose PY12 only when you need the higher tinctorial strength of diarylide for cost-effective high-color-depth inks (especially in low-cost packaging printing). Always verify the specific PY12 grade is certified free from the 24 banned amines — many traditional benzidine-derived PY12 grades are NOT REACH compliant.

FAQ

PY3 vs PY12 Common Questions

Why are some PY12 grades not REACH compliant?

Traditional PY12 was made from 3,3'-dichlorobenzidine which can release banned aromatic amines on cleavage. Modern certified PY12 grades use replacement chemistry that doesn't generate banned amines. Always request the 24-amines-free certificate per shipment from your supplier.

Can I substitute PY3 for PY12 to avoid REACH issues?

Yes — PY3 is inherently REACH compliant when sourced from a certified manufacturer. The shade is cleaner (more greenish) than PY12, so you may need to recalibrate color formulations. PY3 is commonly used as the safer alternative for textile and packaging applications.

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